"Ice states, cyclic exchange and fractional excitations in fermionic and spin models" The quarter-filled Hubbard model extended with nearest neighbor repulsion on the pyrochlore lattice is an insulator for sufficiently large couplings, with an extensive ground state degeneracy. The model can be mapped to the ice- and the 6-vertex problems. The large degeneracy in the ground state manifold can support topological excitations with fractional charge. Similar excitations can arise in the Ising problem, as well as in the classical Heisenberg model with bilinear-biquadratic terms. Quantitative results are presented for the two-dimensional XXZ Heisenberg model, where we discuss the effects of quantum fluctuations and the conditions for spinon deconfinement.